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Oxidation & Rancidity Indices

In short

Oxidation degrades fats and fat-soluble vitamins, and is tracked through peroxide value, anisidine value, TOTOX and free fatty acids — a set that must be read together, not individually.

Measured as: PV in meq O₂/kg; AnV dimensionless; TOTOX = 2·PV + AnV; FFA as % oleic

A low peroxide value can be misleading

Peroxides are intermediates. In an advanced oxidation state they have already decomposed, so peroxide value falls while anisidine value climbs. Reading peroxide value alone can make a badly oxidised oil look fresh, which is why TOTOX exists.

Antioxidant treatment is part of the specification

For fish meal, fish oil, high-fat meals and rendered fats, the antioxidant used, its dose and the date of treatment are as much a part of the specification as the oxidation indices themselves. Untreated marine cargo has a materially shorter usable life.

Typical industrial reference values

Peroxide valueLow single digits desirablePrimary oxidation products
Anisidine valueTracks secondary oxidationRises as PV falls back
TOTOXCombined oxidation historyPreferred for marine oils
Free fatty acidsHydrolytic rather than oxidativeIndicates handling and storage history

Indicative industry reference values for orientation only — always contract against the delivered lot.

What to verify

  • Peroxide value, anisidine value and free fatty acids together, with the sampling date
  • Antioxidant declaration: type, dose, treatment date
  • Temperature history during voyage and storage

Typical risks

  • Vitamin A and E destruction in the finished feed
  • Palatability rejection, particularly in aqua and pet diets
  • Self-heating in bulk marine ingredients

Common mistakes

  • Specifying peroxide value only
  • Ignoring the elapsed time between certificate date and delivery date

Frequently asked questions

Why does oxidation matter beyond the fat itself?

Oxidation propagates. It destroys fat-soluble vitamins and pigments in the same feed, reduces intake, and generates compounds that stress the animal — so the cost is rarely limited to the fat fraction that was measured.

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For commercial farm feed buyers

Buying feed specified on oxidation & rancidity indices for a commercial farm

Best for
Commercial farms, integrators, distributors and feed buyers sourcing feed specified on oxidation & rancidity indices and related feed, additives or nutrition supply on a recurring commercial scale — not pet food, hobby farms or backyard quantities.
Animal species covered
Broilers and layers, dairy and beef cattle, pigs, tilapia, salmon and shrimp, plus sheep and goats on request.
Typical feed buyer needs
A written specification, verified suppliers who can hold that specification, comparable pricing on the same delivery terms, documented quality (CoA, certifications) and a supply schedule that matches production.
Bulk feed and recurring supply
Most requests are bulk or big-bag volumes on monthly or quarterly contracts. Volume per delivery, storage capacity on farm and contract length change price more than the headline per-tonne quote.
Feed additives and premix
Premix, amino acids, minerals, vitamins, enzymes, organic acids, toxin binders and other additives can be quoted alongside compound feed or ingredients so one supplier comparison covers the whole ration.
What affects feed cost
Raw-material origin and specification, inclusion rates, freight and Incoterms, packaging, order volume, payment terms, currency and certification requirements. Landed cost, not ex-works price, decides the winner.
RFQ checklist
Species and production stage, tonnes per month, target specification, delivery port or farm location, packaging, required certifications, first delivery date and contract duration.
Supplier matching process
You define the requirement, FeedMatch structures the RFQ, sends it to relevant qualified suppliers, and returns comparable offers side by side so you can negotiate on equal terms.
Buyer is not charged
Farm buyers are not charged to submit a requirement, receive matched suppliers or compare quotes.

FeedMatch helps farm buyers compare feed suppliers, nutrition providers, additives suppliers and related solutions. FeedMatch is an intermediary and does not manufacture feed or provide financing directly.

Technical parameter names and analytical method references are kept in English because they are quoted verbatim in contracts, certificates and international standards.

Educational reference. FeedMatch Group does not rank, recommend or endorse manufacturers.

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